Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Amphiphilic molecules, comprising hydrophobic and hydrophilic moieties the intrinsic propensity to self-assemble in aqueous environment, sustain a fascinating spectrum of structures functions ranging from biological membranes ordinary soap. Facing challenge design responsive, adaptive, out-of-equilibrium systems water, incorporation photoresponsive motifs amphiphilic molecular offers ample opportunity supramolecular that enables functional responses water non-invasive way using light. Here, we discuss amphiphiles, their self-assembled media at air–water interfaces, various approaches arrive adaptive dynamic isotropic anisotropic systems, including motion interface, foam formation, reversible nanoscale assembly, artificial muscle function. Controlling delicate interplay structural design, self-assembling conditions external stimuli, these responsive amphiphiles open several avenues towards application such as soft materials, controlled delivery or actuators, bridging gap between natural systems.